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A mixed iron(III)/lithium alkoxide

Barley, H.R.L. and Kennedy, A.R. and Mulvey, R.E. (2005) A mixed iron(III)/lithium alkoxide. Acta Crystallographica Section C: Crystal Structure Communications, 61 (7). M346-M347. ISSN 0108-2701

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Abstract

The heterometallic alkoxide catena-poly[[tetra-mu(2)-tert-butoxo-1: 2 kappa(4) O: O; 1: 3 kappa(4) O: O-bis( tetrahydrofuran)-2 kappa O,3 kappa O-iron(III)dilithium( I)]-mu-bromo], [FeLi2Br(C4H9O)(4)(C4H8O)(2)](n), forms a one-dimensional chain through an a-glide. This conformation is achieved through the formation of Fe-III/O/Li/O rings and Li - Br - Li bridges.