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Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation

Andrikopoulos, P.C. and Armstrong, D.R. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 0044-8249

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Conventional meta-deprotonation of toluene leads to resonance of Benzylanionen. But with a new type of bimetallic metalation, the sodium-mediated Magnesierung, can shift the thermodynamic meta-deprotonation in the ring.

Item type: Article
ID code: 651
Keywords: deprotonation, inverse crown compounds, magnesium, metalation, sodium, Chemistry, Medicine(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Professional Services > Learning Services
Unknown Department
Depositing user: Mr Derek Boyle
Date Deposited: 28 Mar 2006
Last modified: 04 Sep 2014 11:55

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