Barnett, N.D.R. and Clegg, W. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate. Chemical Communications (London), 2005 (3). pp. 375-377. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b413191f
Abstract
Relevant to mixtures studied in solution and utilised in styrene polymerisation but hitherto not characterised in the solid, two crystal structures of alkali metal alkoxide-magnesium bis(alkyl) co-complexes have been determined, revealing that in binding to the C2O tripodal face of a common organomagnesiate anion, Na+ prefers O-coordination, whereas K+ prefers C-coordination.
| Item type: | Article |
|---|---|
| ID code: | 644 |
| Keywords: | heterobimetallic alkali, crystal-structure, inverse crown, potassium, chemistry, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 28 Mar 2006 |
| Last modified: | 04 Oct 2012 11:53 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/644 |
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