Barnett, N.D.R. and Clegg, W. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate. Chemical Communications (London), 2005 (3). pp. 375-377. ISSN 0009-241XFull text not available in this repository. (Request a copy from the Strathclyde author)
Relevant to mixtures studied in solution and utilised in styrene polymerisation but hitherto not characterised in the solid, two crystal structures of alkali metal alkoxide-magnesium bis(alkyl) co-complexes have been determined, revealing that in binding to the C2O tripodal face of a common organomagnesiate anion, Na+ prefers O-coordination, whereas K+ prefers C-coordination.
|Keywords:||heterobimetallic alkali, crystal-structure, inverse crown, potassium, chemistry, Chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry
|Depositing user:||Mr Derek Boyle|
|Date Deposited:||28 Mar 2006|
|Last modified:||06 Jan 2017 03:37|