Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b410293b
Abstract
Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.
| Item type: | Article |
|---|---|
| ID code: | 643 |
| Keywords: | magnesium, chemistry, mixed-metal alkyl amide, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 28 Mar 2006 |
| Last modified: | 04 Oct 2012 11:52 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/643 |
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