Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241XFull text not available in this repository. (Request a copy from the Strathclyde author)
Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.
|Keywords:||magnesium, chemistry, mixed-metal alkyl amide, Chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry
|Depositing user:||Mr Derek Boyle|
|Date Deposited:||28 Mar 2006|
|Last modified:||27 Apr 2016 10:57|