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Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

He, X.Y. and Noll, B.C. and Beatty, A. and Mulvey, R.E. and Henderson, K.W. (2004) Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126 (24). pp. 7444-7445. ISSN 0002-7863

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Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

Item type: Article
ID code: 638
Keywords: inverse crown chemistry, magnesium, polymerization, complexes, diisopropylamides, alkoxides, sodium, Chemistry, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
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Depositing user: Mr Derek Boyle
Date Deposited: 28 Mar 2006
Last modified: 04 Sep 2014 12:43
URI: http://strathprints.strath.ac.uk/id/eprint/638

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