Clegg, W. and Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Liddle, S.T. (2003) Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules. Chemical Communications (London), 2003 (3). pp. 406-407. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b211392a
Abstract
While neither KHMDS nor Zn(HMDS)(2) can unilaterally metallate toluene under the conditions studied, the bilateral base 'KZn(HMDS)(3)' can smoothly do so to produce the benzyl product [{KZn(HMDS)(2)(CH2Ph)}(infinity)], which exists in the crystal as an infinite spiral chain of benzyl (ambi-sigma, pi)-linked (KNZnN) rings.
| Item type: | Article |
|---|---|
| ID code: | 610 |
| Keywords: | macrocyclic amide, chemistry, block, magnesium, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 28 Mar 2006 |
| Last modified: | 12 Mar 2012 10:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/610 |
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