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The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by researchers from the Department of Computer & Information Sciences involved in mathematically structured programming, similarity and metric search, computer security, software systems, combinatronics and digital health.

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Hydride encapsulation in s-block metal inverse crown chemistry

Gallagher, D.J. and Henderson, K.W. and Kennedy, A.R. and O'Hara, C.T. and Mulvey, R.E. and Rowlings, R.B. (2002) Hydride encapsulation in s-block metal inverse crown chemistry. Chemical Communications (London), 2002 (4). pp. 376-377. ISSN 0009-241X

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Abstract

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.