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The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs.

Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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TEMPO: a novel chameleonic ligand for s-block metal amide chemistry

Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Rodger, P.J.A. (2001) TEMPO: a novel chameleonic ligand for s-block metal amide chemistry. Chemical Communications (London), 2001 (15). pp. 1400-1401. ISSN 0009-241X

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Abstract

The first structurally characterised examples of the nitroxide TEMPO acting as a ligand towards Li, Na or Mg are described, through a series of hexamethyldisilazide complexes which reveals a remarkable breadth of variety in structure and in the mode of ligation.