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Pushing the frontiers of hard and soft scorpionate chemistry

Dodds, C.A. and Kennedy, A.R. and Reglinski, J. and Spicer, M.D. (2004) Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry, 43 (2). pp. 394-395. ISSN 0020-1669

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Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

Item type: Article
ID code: 583
Keywords: RAY CRYSTAL-STRUCTURES, TRIPODAL LIGANDS, COMPLEXES, DIHYDRATE, SODIUM, MODE, Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user: Mr Derek Boyle
Date Deposited: 20 Mar 2006
Last modified: 04 Sep 2014 12:31
URI: http://strathprints.strath.ac.uk/id/eprint/583

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