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Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

Garner, M. and Lehmann, M.A. and Reglinski, J. and Spicer, M.D. (2001) Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. Organometallics, 20 (24). pp. 5233-5236. ISSN 0276-7333

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Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

Item type: Article
ID code: 556
Keywords: CRYSTAL-STRUCTURE, TRIPODAL LIGANDS, ZINC, HYDROTRIS(METHIMAZOLYL)BORATE, HYDROTRIS(PYRAZOLYL)BORATE, LITHIUM, IONS, HARD, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Unknown Department
Related URLs:
Depositing user: Mr Derek Boyle
Date Deposited: 20 Mar 2006
Last modified: 12 Mar 2012 10:35
URI: http://strathprints.strath.ac.uk/id/eprint/556

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