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(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

Jensen, S.B. and Spicer, M.D. (2001) (eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand. Acta Crystallographica Section E: Structure Reports, 57 (10). o978-o979. ISSN 1600-5368

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Abstract

The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

Item type: Article
ID code: 555
Keywords: crystallography, [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2], diallylphosphine ligand, ruthenium(ii), Physical and theoretical chemistry
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Unknown Department
Related URLs:
Depositing user: Mr Derek Boyle
Date Deposited: 20 Mar 2006
Last modified: 12 Mar 2012 10:35
URI: http://strathprints.strath.ac.uk/id/eprint/555

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