Jensen, S.B. and Spicer, M.D. (2001) (eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand. Acta Crystallographica Section E: Structure Reports, 57 (10). o978-o979. ISSN 1600-5368
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1107/S1600536801015215
Abstract
The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.
| Item type: | Article |
|---|---|
| ID code: | 555 |
| Keywords: | crystallography, [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2], diallylphosphine ligand, ruthenium(ii), Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 20 Mar 2006 |
| Last modified: | 12 Mar 2012 10:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/555 |
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