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Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes

Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214

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Abstract

A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.

Item type: Article
ID code: 535
Keywords: asymmetric catalysis, ligands, nucleophilic additions, polymers, supported catalysis, Chemistry, Organic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Mr Derek Boyle
    Date Deposited: 16 Mar 2006
    Last modified: 04 Sep 2014 13:23
    URI: http://strathprints.strath.ac.uk/id/eprint/535

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