Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1055/s-2005-865238
Abstract
A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.
| Item type: | Article |
|---|---|
| ID code: | 535 |
| Keywords: | asymmetric catalysis, ligands, nucleophilic additions, polymers, supported catalysis, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 16 Mar 2006 |
| Last modified: | 12 Mar 2012 10:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/535 |
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