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Changes in the dielectric relaxations of water in epoxy resin as a function of the extent of water ingress in carbon fibre composites

Boinard, P. and Banks, W.M. and Pethrick, R.A. (2005) Changes in the dielectric relaxations of water in epoxy resin as a function of the extent of water ingress in carbon fibre composites. Polymer, 46 (7). pp. 2218-2229. ISSN 0032-3861

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Abstract

Dielectric relaxation measurements are reported over a frequency range from 10-1 to 109 Hz as a function of exposure time for an epoxy resin-carbon fibre composite, ageing at 60C in water. Investigation of the nature of the dipole relaxation of the water molecules, indicates the nature of their interaction with the polymer matrix. Analysis of the dielectric relaxation spectra allow identification of processes that can be attributed to 'free' and 'bonded' water, water in micro-cracking, located in carbon fibre disbonds and plasticizing the polymer matrix. Identification of the various types of location in which water exists was aided by use of the Ng factor from the Kirkwood-Frölich equation, which describes the constraints on free dipole ration nature imposed by the environment in which it is located. These data indicate the power of the dielectric technique for quantitative analysis of water ingress into epoxy composites.

Item type: Article
ID code: 5047
Keywords: epoxy resin, water ingress, dielectric relaxation spectroscopy, polymer science, chemistry, mechanical engineering, Mechanical engineering and machinery, Chemistry
Subjects: Technology > Mechanical engineering and machinery
Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Faculty of Engineering > Mechanical and Aerospace Engineering
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    Depositing user: Strathprints Administrator
    Date Deposited: 21 Dec 2007
    Last modified: 12 Mar 2012 10:42
    URI: http://strathprints.strath.ac.uk/id/eprint/5047

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