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Atom transfer radical graft polymerization of acrylamide from N-chlorosulfonamidated polystyrene resin, and use of the resin in selective mercury removal

Sonmez, H.B. and Senkal, B.F. and Sherrington, D.C. and Bicak, N. (2003) Atom transfer radical graft polymerization of acrylamide from N-chlorosulfonamidated polystyrene resin, and use of the resin in selective mercury removal. Reactive and Functional Polymers, 55 (1). pp. 1-8. ISSN 1381-5148

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Abstract

Polyacrylamide was grafted from N-chlorosulfonamide groups onto crosslinked polystyrene beads using copper-mediated atom transfer radical polymerization (ATRP) methodology. A beaded polymer with a polyacrylamide surface shell was prepared in four steps, starting from styrene-divinylbenzene (10%) copolymer beads of 210-420 mum particle size: chlorosulfonation; sulfamidation with propylamine; N-chlorination with aqueous hypochloride; and grafting using a concentrated aqueous acrylamide solution with a CuBr-tetramethylethylenediamine complex (1:2). The resulting polymer resin with 84 wt% grafted polyacrylamide has been demonstrated to be an efficient mercury-specific sorbent, able to remove Hg(II) from solutions at ppm levels. No interference arises from common metal ions such as Cd(II), Fe(III), Zn(II), and Pb(II). The sorbed mercury can be eluted by repeated treatment with hot acetic acid without hydrolysis of the amide groups.

Item type: Article
ID code: 499
Keywords: mercury extraction, mercury-specific polystyrene sorbent, grafting by ATRP, polyacrylamide graft, Chemistry, Materials Chemistry, Biochemistry, Polymers and Plastics, Environmental Chemistry, Chemical Engineering(all), Chemistry(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Mr Derek Boyle
    Date Deposited: 09 Mar 2006
    Last modified: 04 Sep 2014 11:45
    URI: http://strathprints.strath.ac.uk/id/eprint/499

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