Bratkowska, Dominika and Davies, Arlene and Fontanals Torroja, Nuria and Cormack, Peter and Borrull, Francesc and Sherrington, David and Marcé, Rosa Maria (2012) Hypercrosslinked strong anion-exchange resin for extraction of acidic pharmaceuticals from environmental water. Journal of Separation Science, 35. pp. 2621-2628. ISSN 1615-9306Full text not available in this repository. (Request a copy from the Strathclyde author)
Two novel high-speciﬁc surface area polymeric sorbents (HXLPP-SAXa and HXLPP-SAXb) were synthesised and evaluated as solid-phase extraction sorbents. The novel sorbents under study are based on hypercrosslinked polymer microspheres and designed speciﬁcally to offer ion-exchange properties; the speciﬁc polymers of interest in the current work have been chemically modiﬁed in such a way as to impart a tuneable level of strong anion-exchange character onto the sorbents. The novel sorbents were applied as strong anion-exchange sorbents in solid-phase extraction studies, with the goal being to selectively extract a group of acidic compounds from complex environmental samples in an efﬁcient manner. Out of two HXLPP-SAX resins evaluated in this study, it was found that the sorbent with the lower ionexchange capacity (HXLPP-SAXa) gave rise to the best overall performance characteristics and, indeed, was found to compare favourably to the solid-phase extraction performance of commercial strong anion-exchange sorbents. When the HXLPP-SAXa sorbent was applied to the solid-phase extraction of environmental water samples, the result showed quantitative and selective extraction of low levels of acidic pharmaceuticals from 500 mL of river water and 100 mL of efﬂuent wastewater.
|Keywords:||anion-exchange resin , environmental water, polymers, Physical and theoretical chemistry, Filtration and Separation, Analytical Chemistry|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||16 Oct 2012 12:00|
|Last modified:||27 Apr 2016 19:09|