Picture of virus under microscope

Research under the microscope...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs.

Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

Explore SIPBS research

Viscosity coefficients of nematic liquid crystals : II. Measurements of some nematic liquid crystals

Orr, Robert and Pethrick, R. A. (2011) Viscosity coefficients of nematic liquid crystals : II. Measurements of some nematic liquid crystals. Liquid Crystals, 38 (9). pp. 1183-1191. ISSN 0267-8292

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Oscillating plate and rotational viscosity measurements are reported for a series of liquid crystals and include n-p-cyano-p-hexylbiphenyl (K18), 4-n-hepthyl-4′-cyanobiphenyl (K21), ethyl-cyclohexyl-ethyl-6-fluoro – n-propyl-biphenyl (I32), n-propyl-cyclohexyl-ethyl-6-fluoro – n-butyl-biphenyl (I43) and a n-pentyl-cyclohexyl-cyanophenyl : n-heptyl-cyclohexyl-cyanophenyl mixture. Rotational viscosity measurements were carried out over a temperature range from ambient to 90°C. Comparison of the values at a temperature of 5 K above the below the clearing point indicate an odd–even effect as the chain length of the hydrocarbon tail is altered. The principle viscosities η1, η2, η3 and η45were measured using an oscillating plate viscometer and the temperature dependences used to calculate the activation energies for flow in the various directions. The magnitude of the activation energy is shown to change with the length of the hydrocarbon chain. The incorporation of the cyclohexyl group imparts flexibility and reduces the activation energy flow, whilst the presence of the fluoro group increases the interactions between molecules, and this is reflected in higher values of the viscosity. The change of viscosity with alignment angle is explored for two of the systems studied and the fit to theory investigated. The Leslie–Ericksen coefficients are calculated for these systems and discussed in terms of changes in the molecular interactions.