Picture of athlete cycling

Open Access research with a real impact on health...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the Physical Activity for Health Group based within the School of Psychological Sciences & Health. Research here seeks to better understand how and why physical activity improves health, gain a better understanding of the amount, intensity, and type of physical activity needed for health benefits, and evaluate the effect of interventions to promote physical activity.

Explore open research content by Physical Activity for Health...

Tetrahedratic mesophases, chiral order, and helical domains induced by quadrupolar and octupolar interactions

Trojanowski, Karol and Pajak, Grzegorz and Longa, L. and Wydro, Thomas (2012) Tetrahedratic mesophases, chiral order, and helical domains induced by quadrupolar and octupolar interactions. Physical Review E, 86 (1). ISSN 1539-3755

[img] PDF
PhysRevE_86_011704.pdf - Final Published Version

Download (1MB)

Abstract

We present an exhaustive account of phases and phase transitions that can be stabilized in the recently introduced generalized Lebwohl-Lasher model with quadrupolar and octupolar microscopic interactions [ L. Longa, G. Pająk and T. Wydro Phys. Rev. E 79 040701 (2009)]. A complete mean-field analysis of the model, along with Monte Carlo simulations allows us to identify four distinct classes of the phase diagrams with a number of multicritical points where, in addition to the standard uniaxial and biaxial nematic phases, the other nematic like phases are stabilized. These involve, among the others, tetrahedratic (T), nematic tetrahedratic (NT), and chiral nematic tetrahedratic (NT*) phases of global Td, D2d, and D2 symmetry, respectively. Molecular order parameters and correlation functions in these phases are determined. We conclude with generalizations of the model that give a simple molecular interpretation of macroscopic regions with opposite optical activity (ambidextrous chirality), observed, e.g., in bent-core systems. An estimate of the helical pitch in the NT* phase is also given.