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Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Cadenbach, Thomas and Hevia, Eva and Kennedy, Alan and Mulvey, Robert E. and Pickrell, Janie-Anne and Robertson, Stuart D. (2012) Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire. Dalton Transactions, 41 (34). pp. 10141-10144. ISSN 1477-9226

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Abstract

New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

Item type: Article
ID code: 41090
Keywords: low denticity , coordination modes , high denticity , tripodal ligand , coordinative repertoire, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 11 Sep 2012 15:48
Last modified: 27 Mar 2014 10:29
URI: http://strathprints.strath.ac.uk/id/eprint/41090

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