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Superelectrophilic amidine dications : dealkylation by triflate anion

Kovacevic, Luka S and Idziak, Christopher and Markevicius, Augustinas and Scullion, Callum and Corr, Michael James and Kennedy, Alan and Tuttle, Tell and Murphy, John A (2012) Superelectrophilic amidine dications : dealkylation by triflate anion. Angewandte Chemie International Edition, 51 (34). pp. 8516-8519. ISSN 1433-7851

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Abstract

Formamides were designed that when treated with triflic anhydride would be transformed into superelectrophilic amidine dications. These dications were so electrophilic that they underwent in situ dealkylation by the triflate anion (see scheme; Tf=trifluoromethanesulfonyl).

Item type: Article
ID code: 40435
Keywords: cations, methionine, methyl transfer, nucleophilic substitution, superelectrophiles, Chemistry, Electrochemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Technology and Innovation Centre > Bionanotechnology
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Depositing user: Pure Administrator
Date Deposited: 17 Jul 2012 15:10
Last modified: 27 Mar 2014 10:18
URI: http://strathprints.strath.ac.uk/id/eprint/40435

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