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Superelectrophilic amidine dications : dealkylation by triflate anion

Kovacevic, Luka S and Idziak, Christopher and Markevicius, Augustinas and Scullion, Callum and Corr, Michael James and Kennedy, Alan and Tuttle, Tell and Murphy, John A (2012) Superelectrophilic amidine dications : dealkylation by triflate anion. Angewandte Chemie International Edition, 51 (34). pp. 8516-8519. ISSN 1433-7851

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Abstract

Superelectrophiles: Formamides were designed that when treated with triflic anhydride would be transformed into superelectrophilic amidine dications. These dications were so electrophilic that they underwent in situ dealkylation by the triflate anion (see scheme; Tf = trifluoromethanesulfonyl). DFT calculations were used to determine the mechanistic details of the dealkylation reaction.

Item type: Article
ID code: 40435
Notes: Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords: amidines, anions, cations, dealkylation, mesylates, methionine, molecular structure, superelectrophiles, Physical and theoretical chemistry, Physical and Theoretical Chemistry
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Technology and Innovation Centre > Bionanotechnology
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 17 Jul 2012 15:10
Last modified: 09 Jun 2014 11:20
URI: http://strathprints.strath.ac.uk/id/eprint/40435

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