Kovacevic, Luka S and Idziak, Christopher and Markevicius, Augustinas and Scullion, Callum and Corr, Michael James and Kennedy, Alan and Tuttle, Tell and Murphy, John A (2012) Superelectrophilic amidine dications : dealkylation by triflate anion. Angewandte Chemie International Edition, 51 (34). pp. 8516-8519. ISSN 1433-7851
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/anie.201202990
Abstract
Formamides were designed that when treated with triflic anhydride would be transformed into superelectrophilic amidine dications. These dications were so electrophilic that they underwent in situ dealkylation by the triflate anion (see scheme; Tf=trifluoromethanesulfonyl).
| Item type: | Article |
|---|---|
| ID code: | 40435 |
| Keywords: | cations, methionine, methyl transfer, nucleophilic substitution, superelectrophiles, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 17 Jul 2012 15:10 |
| Last modified: | 15 May 2013 11:11 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/40435 |
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