Baillie, Sharon E. and Blair, Victoria L. and Blakemore, David C. and Hay, Duncan and Kennedy, Alan and Pryde, David C. and Hevia, Eva (2012) New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation. Chemical Communications, 48 (14). pp. 1985-1987. ISSN 1359-7345
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/c2cc16959b
Abstract
Comparing the reactivity of the related lithium zincates [(THF)LiZn(TMP)Bu-t(2)] (1) and [(PMDETA)(LiZnBu3)-Bu-t] (2) towards pyrazine discloses two new bimetallic approaches for the selective 2,5-dideprotonation and room temperature C-H alkylation of this sensitive heterocycle.
| Item type: | Article |
|---|---|
| ID code: | 39971 |
| Keywords: | functionalisation , pyrazine, dideprotozincation , nucleophilic alkylation, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 08 Jun 2012 14:32 |
| Last modified: | 08 Jun 2012 14:32 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/39971 |
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