Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

Baillie, Sharon E. and Blair, Victoria L. and Blakemore, David C. and Hay, Duncan and Kennedy, Alan and Pryde, David C. and Hevia, Eva (2012) New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation. Chemical Communications, 48 (14). pp. 1985-1987. ISSN 1359-7345

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Comparing the reactivity of the related lithium zincates [(THF)LiZn(TMP)Bu-t(2)] (1) and [(PMDETA)(LiZnBu3)-Bu-t] (2) towards pyrazine discloses two new bimetallic approaches for the selective 2,5-dideprotonation and room temperature C-H alkylation of this sensitive heterocycle.

Item type: Article
ID code: 39971
Keywords: functionalisation , pyrazine, dideprotozincation , nucleophilic alkylation, Physical and theoretical chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 08 Jun 2012 14:32
Last modified: 05 Sep 2014 16:17
URI: http://strathprints.strath.ac.uk/id/eprint/39971

Actions (login required)

View Item