Garden, Jennifer A. and Kennedy, Alan and Mulvey, Robert E. and Robertson, Stuart D. (2012) Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency. Chemical Communications, 48 (43). pp. 5265-5267. ISSN 1359-7345
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/c2cc31793a
Abstract
Sodium TMP-zincate, [(TMEDA)Na(TMP)(Bu-t)Zn(Bu-t)], can deproto-zincate N-Boc pyrrolidine at ambient temperature in hexane solution, whereas in toluene the captured alpha-carbanion of the heterocycle attacks the solvent setting off a cascade of reactions that ultimately produce a pyrrolidine-substituted enolate.
| Item type: | Article |
|---|---|
| ID code: | 39877 |
| Keywords: | zincation , N-Boc pyrrolidine , solvent dependency, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 30 May 2012 16:14 |
| Last modified: | 30 May 2012 16:14 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/39877 |
Actions (login required)
| View Item |