Audouard, Christophe and Garayt, Maxime R and Kerouredan, Erwan and Percy, Jonathan and Yang, Hongli (2005) A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol. Journal of Fluorine Chemistry, 126 (4). 609–621.
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/j.jfluchem.2005.01.005
Abstract
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.
| Item type: | Article |
|---|---|
| ID code: | 38972 |
| Keywords: | Trifluoroethanol, Difluoro, Acylsilane, Dehydrofluorination/metallation, Synthesis, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 04 Apr 2012 16:48 |
| Last modified: | 09 Jul 2012 11:25 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38972 |
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