Audouard, Christophe and Garayt, Maxime R and Kerouredan, Erwan and Percy, Jonathan and Yang, Hongli (2005) A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol. Journal of Fluorine Chemistry, 126 (4). 609–621.Full text not available in this repository. (Request a copy from the Strathclyde author)
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.
|Keywords:||Trifluoroethanol, Difluoro, Acylsilane, Dehydrofluorination/metallation, Synthesis, Chemistry, Biochemistry, Organic Chemistry, Environmental Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||04 Apr 2012 15:48|
|Last modified:||05 May 2016 00:22|