Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation

Fawcett, John and Griffiths, Gerry A and Percy, Jonathan and Pintat, Stephane and Smith, Clive A and Spencer, Neil S and Uneyama, Emi (2004) Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation. Chemical Communications, 2004 (3). pp. 302-303. ISSN 1359-7345

Preview

PDF - Published Version
Download (113Kb) | Preview

Official URL: http://dx.doi.org/10.1039/b313813e

Abstract

Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.

Item type:	Article
ID code:	38971
Keywords:	difluorosugar analogues, difluorinated cyclooctenones, hydroxyl groups, Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user:	Pure Administrator
Date Deposited:	04 Apr 2012 16:45
Last modified:	20 Jun 2012 14:58
URI:	http://strathprints.strath.ac.uk/id/eprint/38971

Actions (login required)

View Item

Towards conformationally-locked difluorosugar analogues : an unexpected sense of dihydroxylation

Abstract

Actions (login required)

Fulltext Downloads: