Fawcett, John and Griffith, Gerry A and Percy, Jonathan and Uneyama, Emi (2004) Unexpectedly selective formation and reactions of epoxycyclooctenones under microwave-mediated conditions. Organic Letters, 6 (8). pp. 1277-1280. ISSN 1523-7060
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/ol0496327
Abstract
Topologically mobile difluorinated cyclooctenones undergo rapid, high-yielding, and completely stereoselective epoxidations with methyl-(trifluoromethyl)dioxirane. The epoxides resist conventional hydrolysis but react smoothly in basic media under microwave irradiation to afford unique hemiacetals and hemiaminals in good yield.
| Item type: | Article |
|---|---|
| ID code: | 38966 |
| Keywords: | difluorinated cyclooctenones, stereoselective epoxidations, methyl(trifluoromethyl)dioxirane, hydrolysis, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 04 Apr 2012 16:30 |
| Last modified: | 04 Apr 2012 16:30 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38966 |
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