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Rapid syntheses of difluorinated dihydropyrans

Percy, Jonathan and Pintat, Stephane (2000) Rapid syntheses of difluorinated dihydropyrans. Chemical Communications, 2000 (7). pp. 607-608. ISSN 1359-7345

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Abstract

A very short reaction sequence opens with metal-mediated addition of commercial bromodifluoropropene to aldehydes; allylation under phase transfer catalysed conditions sets the stage for a ring closing metathesis (RCM) in the presence of commercial Grubbs’ catalyst to afford potentially useful difluorinated dihydropyrans.

Item type: Article
ID code: 38949
Keywords: commercial bromodifluoropropene , aldehydes, ring closing, difluorinated dihydropyrans, rapid syntheses , Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date Deposited: 04 Apr 2012 13:44
Last modified: 21 May 2015 14:29
URI: http://strathprints.strath.ac.uk/id/eprint/38949

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