Baker, Daniel R. and Clegg, William and Horsburgh, Lynne and Mulvey, Robert (1994) Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment. Organometallics, 13 (11). pp. 4170-4172. ISSN 0276-7333
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/om00023a017
Abstract
Mixed-alkali-metal metalation of toluene in the presence of TMEDA produces the benzyl complex [(PhCH(2))(4)Li2-xNa2+x(TMEDA)(4)], which has an octagonal ring structure that, in. spite of the 4-fold aggregation, contains Li+ cations complexed by bidentate TMEDA, a situation normally sterically forbidden in, homometallic lithium tetramers.
| Item type: | Article |
|---|---|
| ID code: | 38837 |
| Keywords: | structural characterisitcs, crystal structure, alkali, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 30 Mar 2012 12:51 |
| Last modified: | 30 Mar 2012 12:51 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38837 |
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