Barnett, N.D.R. and Mulvey, Robert and CLEGG, W and ONEIL, P A (1993) Butyllithium cubane tetramers linked by Li-TMEDA-Li bridges in an infinite, zig-zag chain arrangement: first crystallographic study of a simple butyl compound of an early main group element. Journal of the American Chemical Society, 115 (4). pp. 1573-1574. ISSN 0002-7863
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/ja00057a051
Abstract
Herein we report the structure of the crystalline alkyllithium complex [((BU~L~)~.TMEDA(B],u] nLi,n -butyllithium; TMEDA, N,N,NW'-tetramethylethylenediamine)w hich, to the best of our knowledge, is the first crystal structure of a simple butyl derivative of a group 1 (Li, Na, etc.) or a group 2 (Be, Mg, etc.) metal (Le. of formula "BunMn or *Bun2Mn).
| Item type: | Article |
|---|---|
| ID code: | 38834 |
| Keywords: | organo-lithium compounds, crystal structure, solid state, Tetrahydrofuran, spectroscopy, reactivity, C-13-NMR, complex, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 30 Mar 2012 12:26 |
| Last modified: | 30 Mar 2012 12:26 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38834 |
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