Andrews, Philip C. and Baker, Daniel R. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1991) Isostructural potassium and sodium di-nitrogen functionalized amides: Syntheses and crystal structures of [Ph(2-Pyr)NK·TMEDA]2 and [Me(2-Pyr)NNa·TMEDA]2. Polyhedron, 10 (15). pp. 1839-1841. ISSN 0277-5387
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/S0277-5387(00)83809-7
Abstract
Two alkali metal amide complexes, [Ph(2-Pyr)NK.TMEDA]2 and [Me(2-Pyr)NNa.TMEDA]2, synthesized from 1:1:1 mixtures of PhM (M = K or Na), the appropriate secondary amine and the Lewis base TMEDA, have been structurally identified by X-ray diffraction and shown to adopt analogous dimeric structures based on planar (N-M)2 rings with additional "internal"- and "external"-donor N.M links that render the metal cations six-coordinate.
| Item type: | Article |
|---|---|
| ID code: | 38830 |
| Keywords: | alkali, potassium, sodium, amides, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 30 Mar 2012 12:06 |
| Last modified: | 30 Mar 2012 12:06 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38830 |
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