Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Triazoles from N-alkynylheterocycles and their coordination to iridium

Burley, Glenn and Davies, David (2012) Triazoles from N-alkynylheterocycles and their coordination to iridium. Organometallics, 31 (3). 1112–1117. ISSN 0276-7333

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

N-alkynylheterocycles (benzimidazole and indazole) are converted to triazoles by click chemistry, and the resulting triazoles react with [IrCl2Cp*]2. The benzimidazole-triazole coordinates in a monodentate fashion through the benzimidazole, whereas the indazole-triazole is bidentate through coordination of both heterocycles. Reaction of the benzimidazole-triazole with methyliodide gives a benzimidazolium salt that deprotonates on coordination to afford a rare example of a bidentate NHC–triazole.

Item type: Article
ID code: 38536
Keywords: ynamine, N-alkynylheterocycles , triazoles, iridium, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Technology and Innovation Centre > Bionanotechnology
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 16 Mar 2012 14:58
Last modified: 05 Sep 2014 15:32
URI: http://strathprints.strath.ac.uk/id/eprint/38536

Actions (login required)

View Item