Burley, Glenn and Davies, David (2012) Triazoles from N-alkynylheterocycles and their coordination to iridium. Organometallics, 31 (3). 1112–1117. ISSN 0276-7333
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/om201157g
Abstract
N-alkynylheterocycles (benzimidazole and indazole) are converted to triazoles by click chemistry, and the resulting triazoles react with [IrCl2Cp*]2. The benzimidazole-triazole coordinates in a monodentate fashion through the benzimidazole, whereas the indazole-triazole is bidentate through coordination of both heterocycles. Reaction of the benzimidazole-triazole with methyliodide gives a benzimidazolium salt that deprotonates on coordination to afford a rare example of a bidentate NHC–triazole.
| Item type: | Article |
|---|---|
| ID code: | 38536 |
| Keywords: | ynamine, N-alkynylheterocycles , triazoles, iridium, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 16 Mar 2012 14:58 |
| Last modified: | 16 Mar 2012 14:58 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38536 |
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