Clegg, W. and Davies, R.P. and Dunbar, Lorraine and Feeder, N and Liddle, S.T. and Mulvey, Robert and Snaith, R. and Wheatley, A.E.H. (1999) Lithiated organophosphorus enamines : a new synthetic approach and the first crystal structures. Chemical Communications, 1999 (15). pp. 1401-1402. ISSN 1359-7345
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/A903175H
Abstract
Made by a nitrile insertion/hydrogen migration process via Ph2P(O)CH2Li and (BuCN)-C-t, the enamide Ph2P(O)CH=C(Bu-t)N(H)Li and its TMEDA hemisolvate exist as tetrameric and dinuclear arrangements respectively: the novel structure of the starting lithiated phosphane oxide, also in its TMEDA hemisolvated form, is shown to contain Li-C contacts of two distinct types.
| Item type: | Article |
|---|---|
| ID code: | 38351 |
| Keywords: | phosphane oxide, crystal structure, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 09 Mar 2012 10:05 |
| Last modified: | 12 Mar 2012 11:50 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38351 |
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