Clegg, W and Horsburgh, L. and Couper, S.A. and Mulvey, Robert (1999) catena-Poly[[bis(mu-2,6-dimethylpiperidin-ido-N:N)dilithium]-mu-(N,N,N ',N '-tetra- methylethylenediamine-N : N'')]. Acta Crystallographica Section C: Crystal Structure Communications, 55 (6). pp. 867-869. ISSN 0108-2701
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1107/S0108270199001171
Abstract
The title compound, [Li-2(C7H14N)(2)(C6H16N2)](n), is a chain polymer in which strictly planar Li2N2 rings incorporating 2,6-dimethylpiperidinido ligands are linked by N,N,N',N'-tetramethylethylenediamine ligands in a rare bridging role. The Li atom is planar three-coordinate. The internal ring angles are obtuse [107.89(11)degrees] at lithium and acute [72.11(11)degrees] at nitrogen, as is commonly found for lithium amide ring structures.
| Item type: | Article |
|---|---|
| ID code: | 38349 |
| Keywords: | lithium diisopropylamide, N,N,N',N'-tetramethylethylenediamine, units, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 09 Mar 2012 09:22 |
| Last modified: | 12 Mar 2012 11:50 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38349 |
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