Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/A904800F
Abstract
Synthesised from its homonuclear components in the presence of the Lewis base TMEDA, the title heteronuclear alkoxide crystallises in an unsolvated TMEDA-free form; its novel breastplate-like Li4K4O8 cage structure, which undergoes an exchange process in arene solution as determined by dynamic NMR spectroscopic studies, displays a planar K-4 arrangement in marked contrast to the tetrahedral K-4 arrangement found in homonuclear [((BuOK)-O-t)(4)].
| Item type: | Article |
|---|---|
| ID code: | 38327 |
| Keywords: | solid state structure , metal alkoxides, complex structures, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 08 Mar 2012 14:12 |
| Last modified: | 12 Mar 2012 11:50 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38327 |
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