Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345Full text not available in this repository. (Request a copy from the Strathclyde author)
Synthesised from its homonuclear components in the presence of the Lewis base TMEDA, the title heteronuclear alkoxide crystallises in an unsolvated TMEDA-free form; its novel breastplate-like Li4K4O8 cage structure, which undergoes an exchange process in arene solution as determined by dynamic NMR spectroscopic studies, displays a planar K-4 arrangement in marked contrast to the tetrahedral K-4 arrangement found in homonuclear [((BuOK)-O-t)(4)].
|Keywords:||solid state structure , metal alkoxides, complex structures, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||08 Mar 2012 14:12|
|Last modified:||27 Apr 2016 18:21|