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Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

Clegg, W and Drummond, A M and Mulvey, Robert and Liddle, S T (1998) Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges. Chemical Communications (21). pp. 2391-2392. ISSN 1359-7345

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Abstract

Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.