Clegg, W and Horsburgh, L and Lindsay, D M and Mulvey, Robert (1998) Diphenylzirconocene. Acta Crystallographica Section C: Crystal Structure Communications, 54. pp. 315-317. ISSN 0108-2701Full text not available in this repository. (Request a copy from the Strathclyde author)
The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.
|Keywords:||diphenylzirconocene, tetrahedral geometry, Chemistry, Biochemistry, Genetics and Molecular Biology(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||06 Mar 2012 12:50|
|Last modified:||22 Mar 2017 12:02|