Clegg, W and Horsburgh, L and Mulvey, Robert and Rowlings, R (1996) The first magnesium amide trimer, magnesio-1,8-diaminonaphthalene center dot hexamethylphosphoramide: introducing an unprecedented cage assembly incorporating an Mg-3 unit within a N-6 trigonal prism. Chemical Communications (15). pp. 1739-1740. ISSN 1359-7345Full text not available in this repository. (Request a copy from the Strathclyde author)
Doubly deprotonating 1,8-diaminonaphthalene with dibutylmagnesium in the presence of hmpa leads to the formation of the title compound, which establishes a new aggregation state and cage architecture within magnesium amide chemistry; the departure from classical, non-cage, organomagnesium structures can be attributed to the bifunctional and steric design of the involved 'dianion'.
|Keywords:||organomagnesium compounds, rays, magnesium amide trimer , clusters, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||06 Mar 2012 12:45|
|Last modified:||27 Apr 2016 18:20|