Clegg, W and Horsburgh, L and Mulvey, Robert and Rowlings, R (1996) The first magnesium amide trimer, magnesio-1,8-diaminonaphthalene center dot hexamethylphosphoramide: introducing an unprecedented cage assembly incorporating an Mg-3 unit within a N-6 trigonal prism. Chemical Communications (15). pp. 1739-1740. ISSN 1359-7345
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/CC9960001739
Abstract
Doubly deprotonating 1,8-diaminonaphthalene with dibutylmagnesium in the presence of hmpa leads to the formation of the title compound, which establishes a new aggregation state and cage architecture within magnesium amide chemistry; the departure from classical, non-cage, organomagnesium structures can be attributed to the bifunctional and steric design of the involved 'dianion'.
| Item type: | Article |
|---|---|
| ID code: | 38193 |
| Keywords: | organomagnesium compounds, rays, magnesium amide trimer , clusters, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 06 Mar 2012 12:45 |
| Last modified: | 12 Mar 2012 11:49 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38193 |
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