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Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

Clegg, W. and O'Neil, P.A. and Henderson, K.W. and Mulvey, Robert (1993) Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]. Acta Crystallographica Section C: Crystal Structure Communications, 49 (12). pp. 2108-2109. ISSN 0108-2701

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Abstract

trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.