Mulvey, Robert and Dunbar, Lorraine and Clegg, W. and Horsburgh, L. (1996) Stoichiometric dependence of the long-established reaction of butyllithium with pyridine : A hidden secondary reaction that produces a pyridine adduct of a lithiodihydropyridine. Angewandte Chemie. International edition in English, 35 (7). pp. 753-755. ISSN 0570-0833
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/anie.199607531
Abstract
By adding more than three molar equivalents of pyridine to n-butyllithium, a new reaction has been, uncovered in which the novel bis(pyridine)dihydropyridyllithium dimer 1 is formed. The reduction process formally involves transfer of an in situ form of lithium hydride.
| Item type: | Article |
|---|---|
| ID code: | 38160 |
| Keywords: | dihydropyridine, heterocycles, hydride transfer, lithium compounds, structure elucidation, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 05 Mar 2012 15:06 |
| Last modified: | 04 Oct 2012 14:14 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38160 |
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