Barker, James and Barnett, N.D.R. and Barr, Donald and CLEGG, W and Mulvey, Robert and O'Neil, P.A. (1993) Crystal Structure of [(-Cyanoisopropyl-sodium · Tetramethylenediamine)4 : How Coordination Expansion from Li to Na Centers can Increase the Aggregation State of an -Nitrile “Carbanion”. Angewandte Chemie International Edition, 32 (9). pp. 1366-1368. ISSN 1433-7851Full text not available in this repository. (Request a copy from the Strathclyde author)
A tetrameric contact ion pair structure with a distorted cubane (NNa)4 core is revealed for the title complex 1. The structures of such -nitrile “carbanions”–important intermediates in organic chemistry–are dependent on the identity of the metal employed, as a comparison with the related complex 2 with an (NLi)2 ring shows.
|Keywords:||stacking, lithium, cubane, rings, Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||05 Mar 2012 14:52|
|Last modified:||30 Apr 2016 00:09|