Barr, Donald and Clegg, William and Cowton, Lucy and Horsburgh, Lynn and Mackenzie, Fiona M. and Mulvey, Robert (1995) Lithium anilide complexed by pmdeta : expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium. Journal of the Chemical Society, Chemical Communications, 1995 (8). pp. 891-892. ISSN 0022-4936Full text not available in this repository. (Request a copy from the Strathclyde author)
Lithium structural chemistry continues to surprise as highlighted here by the reaction of Bu(n)Li, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.
|Keywords:||amide chemistry, crystal, adduct, ring, lithium anilide, Chemistry, Molecular Medicine|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||05 Mar 2012 14:25|
|Last modified:||22 Mar 2017 12:01|