Barr, Donald and Clegg, William and Cowton, Lucy and Horsburgh, Lynn and Mackenzie, Fiona M. and Mulvey, Robert (1995) Lithium anilide complexed by pmdeta : expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium. Journal of the Chemical Society, Chemical Communications, 1995 (8). pp. 891-892. ISSN 0022-4936
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
Lithium structural chemistry continues to surprise as highlighted here by the reaction of Bu(n)Li, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.
| Item type: | Article |
|---|---|
| ID code: | 38152 |
| Keywords: | amide chemistry, crystal, adduct, ring, lithium anilide, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 05 Mar 2012 14:25 |
| Last modified: | 12 Mar 2012 11:49 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38152 |
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