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Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

Clegg, W. and Horsburgh, L. and Mulvey, Robert and Ross, M.J. (1994) Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine. Journal of the Chemical Society, Chemical Communications, 1994 (20). pp. 2393-2394. ISSN 0022-4936

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Abstract

The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.