Clegg, W. and Frank, Michael and Mulvey, Robert and O'Neil, P.A. (1994) Synthesis and X-ray crystallographic characterisation of o-phenylenediamidomagnesium·tetrahydrofuran : the first octahedral Mg6 cluster. Journal of the Chemical Society, Chemical Communications, 1994 (1). pp. 97-98. ISSN 0022-4936Full text not available in this repository. (Request a copy from the Strathclyde author)
Crystals of o-phenylenediamidomagnesium tetrahydrofuran prepared at the interface of a sec-butyl-n-butyl magnesium in heptane-o-phenylenediamine in THF bilayered solution, have been shown by an X-ray diffraction study to consist of unprecedented, discrete octahedral Mg-6 clusters, held in place by six bridging, divalent, N-bonding ligands, and solvated by THF molecules to give the Mg atoms a five-coordinate, square-based pyramidal geometry overall.
|Keywords:||structural analysis, amides, reagent, Chemistry, Molecular Medicine|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||05 Mar 2012 13:59|
|Last modified:||05 May 2016 00:20|