Clegg, W. and Henderson, Kenneth W. and Mulvey, Robert and O'Neil, P.A. (1993) Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] : a new type of magnesiate complex free of a donor solvent as ligand. Journal of the Chemical Society, Chemical Communications, 1993 (11). pp. 969-970. ISSN 0022-4936
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/C39930000969
Abstract
A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.
| Item type: | Article |
|---|---|
| ID code: | 38146 |
| Keywords: | aryl compounds, metal alkyl, crystal structure, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 05 Mar 2012 13:47 |
| Last modified: | 12 Mar 2012 11:49 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/38146 |
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