Armstrong, David. R. and Clegg, W. and MacGregor, M. and Mulvey, Robert and O'Neil, P.A. (1993) Butyllithium-induced cyclotrimerisation reactions of organic nitriles : solvent dependency, crystal and solution structures of lithio triazine intermediates and an unexpected rearrangement of dihydrotriazino anions. Journal of the Chemical Society, Chemical Communications, 1993 (7). pp. 608-610. ISSN 0022-4936Full text not available in this repository. (Request a copy from the Strathclyde author)
Sequential addition of Bu(t)C=N and PhC=N (2 equiv.) to Bu(n)Li in the presence of tetrahydrofuran (THF) produces an isolable lithio 1,4-dihydrotriazine tris(THF)solvate, characterised by both NMR spectroscopic and X-ray crystallographic methods, which converts to a 1,2-dihydro arrangement on methanolysis.
|Keywords:||organic nitriles, lithio triazine, dihydrotriazino anions, Chemistry, Molecular Medicine|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||05 Mar 2012 12:00|
|Last modified:||27 Apr 2016 18:19|