Marcinek, Andrzej and Zielonka, Jacek and Gebicki, Jerzy and Gordon, Charles M. and Dunkin, Ian R. (2001) Ionic liquids: novel media for characterisation of radical ions. Journal of Physical Chemistry A, 105 (40). pp. 9305-9309. ISSN 1089-5639
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
The novel application of ionic liquids as media for radiolytic generation and UV−vis−NIR spectroscopic characterization of radical ions is described. The redox properties of neat 1-butyl-3-methylimidazolium salts and their aqueous solutions have been investigated by means of pulse radiolysis. Furthermore, ionic liquids prove to be ideal media for the simultaneous generation of radical cations and anions. The radical cations generated from 1-methyl-1,4-dihydronicotinamide, a structural analogue of NADH, have been spectroscopically characterized under matrix conditions for the first time.
| Item type: | Article |
|---|---|
| ID code: | 37603 |
| Keywords: | ionic liquids , radiolytic generation , spectroscopic characterization , radical ions, pulse radiolysis, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 13 Feb 2012 12:38 |
| Last modified: | 12 Mar 2012 11:47 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37603 |
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