Andrews, Philip C. and Armstrong, David R. and Mulvey, Robert and Reed, David (1988) Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n. Journal of the American Chemical Society, 110 (15). pp. 5235-5236. ISSN 0002-7863
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/ja00223a076
Abstract
In organolithium chemistry evidence is accumulating that lithium atoms situated in abnormally low coordination environments then proceed to interact with nearby CH units of the ligands. For example, the crystal structure of [(PhCH,),NLi], revealed a planar (NLi)3 ring whose formally just two-coordinate metal atoms form close contacts with CHpCoCH portions of the benzyl groups.
| Item type: | Article |
|---|---|
| ID code: | 37564 |
| Keywords: | carbon-hydrogen bonds, organolithium chemistry, carbon-hydrogen bonds, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 09 Feb 2012 19:23 |
| Last modified: | 12 Mar 2012 11:47 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37564 |
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