Barr, D. and Snaith, R. and Mulvey, Robert and Reed, D. (1988) Characterization of the bis(pyridine) complex of the butyllithium-pyridine adduct, 2-Bun(C5H5N)Li·(C5H5N)2; its decomposition to 2-butylpyridine via a dihydropyridine. Polyhedron, 7 (8). pp. 665-668. ISSN 0277-5387
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/S0277-5387(00)80376-9
Abstract
The complexed adduct, 2-Bun(C5H5N)Li·(C5H5N)2, (3), synthesized by reaction of BunLi with a three-fold excess of pyridine, has been characterized. 1H NMR studies on solutions of (3) of various ages and histories (thermal and photochemical) have shown that the adduct deteriorates to the hydrolysis product 2-butylpyridine (1) via 1,2-dihydro-2-butylpyridine (4).
| Item type: | Article |
|---|---|
| ID code: | 37563 |
| Keywords: | pyridine, 2-butylpyridine, dihydropyridine, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 09 Feb 2012 18:54 |
| Last modified: | 12 Mar 2012 11:47 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37563 |
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