BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and SNAITH, R and WRIGHT, D S (1988) Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications (2). pp. 145-147. ISSN 0022-4936
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/C39880000145
Abstract
The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.
| Item type: | Article |
|---|---|
| ID code: | 37530 |
| Keywords: | lithium thiocyanate , polymeric solid , solution structures, crystal structures, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 09 Feb 2012 15:05 |
| Last modified: | 12 Mar 2012 11:46 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37530 |
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