BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and SNAITH, R and WRIGHT, D S (1988) Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications (2). pp. 145-147. ISSN 0022-4936Full text not available in this repository. (Request a copy from the Strathclyde author)
The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.
|Keywords:||lithium thiocyanate , polymeric solid , solution structures, crystal structures, Physical and theoretical chemistry, Molecular Medicine|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||09 Feb 2012 15:05|
|Last modified:||22 Mar 2017 12:00|