Picture of person typing on laptop with programming code visible on the laptop screen

World class computing and information science research at Strathclyde...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by researchers from the Department of Computer & Information Sciences involved in mathematically structured programming, similarity and metric search, computer security, software systems, combinatronics and digital health.

The Department also includes the iSchool Research Group, which performs leading research into socio-technical phenomena and topics such as information retrieval and information seeking behaviour.

Explore

The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4

CLEGG, W and Mulvey, Robert and SNAITH, R and TOOGOOD, G E and WADE, K (1986) The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4. Journal of the Chemical Society, Chemical Communications (23). pp. 1740-1742. ISSN 0022-4936

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

A mixed alkali metal guanidino complex LiNa3[OP(NMe2)3]3[NC(NMe2)2]4(1), the first compound of its type, has been synthesised from BunLi, BunNa, OP(NMe2)3, and HNC(NMe2)2; an X-ray crystallographic study shows it to be a cubane-type cluster built up of novel µ3-N–LiNa2 and µ3-N–Na3 pyramids though additional Li H–C interactions are indicated.