BARR, D and SNAITH, R and Mulvey, Robert and WADE, K and REED, D (1986) Variable-temperature and-concentration 1H and 7Li NMR studies of solutions of hexameric iminolithium compounds, (R1R2CNLi)6. Magnetic Resonance in Chemistry, 24 (8). pp. 713-717.Full text not available in this repository. (Request a copy from the Strathclyde author)
Variable-temperature 7Li and proton NMR spectra of four hexameric (in the solid state) iminolithium compounds, (R1R2CNLi)6 [where R1 = Me2N,R2= Ph (1), R1 = R2 = Me2N (2), R1 = But, R2 = Ph (3) and R1 = R2 = But (4)], recorded for toluene-d8, solutions of differing concentrations, are described, and the results are discussed with respect to known solid-state structures. Complex equilibria, probably involving trimeric units and higher aggregates than hexamers, have been detected at low temperatures for solutions of 1 and 2, although similar equilibria do not occur, or are too rapid to detect even at the lowest temperatures attainable, for solutions of 3 and 4.
|Keywords:||hexameric iminolithium compounds , iminolithium compounds, hexamers, Physical and theoretical chemistry, Materials Science(all), Chemistry(all)|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||08 Feb 2012 15:51|
|Last modified:||28 Oct 2016 02:32|