BARR, D and HUTTON, K B and MORRIS, J H and Mulvey, Robert and REED, D and SNAITH, R (1986) The isolation of a highly arene-soluble alkali metal tetrafluoroborate complex, LiBF4·4HMPA [HMPA = OP(NMe2)3]: evidence for strong Li F interactions in solution. Journal of the Chemical Society, Chemical Communications (2). pp. 127-129. ISSN 0022-4936
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/C39860000127
Abstract
Reaction of BF3·OEt2 with 3 (BunLi·HMPA)[HMPA = OP(NMe2)3] has been monitored by variable-temperature 7Li and 11B n.m.r. spectroscopy and shown to produce a highly arene-soluble, crystalline complex, LiBF4·4HMPA, (1); spectroscopic, cryoscopic, and conductimetric measurements indicate that this exists in solution as tight lithium and tetrafluoroborate components held by Li F interactions.
| Item type: | Article |
|---|---|
| ID code: | 37490 |
| Keywords: | arene-soluble alkali , tetrafluoroborate complex, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 08 Feb 2012 15:39 |
| Last modified: | 12 Mar 2012 11:46 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37490 |
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